Elaboration and Characterization of Ni-Zn Thin Films on AICI 430 stainless steel by Co-Sputtering Magnetron

Authors

  • Samy Anas
  • Naima Zaourar Boutarek
  • Philippe David
  • Eric Mossang
  • Samir Mansour
  • Faouzi Messaoud

DOI:

https://doi.org/10.22399/ijcesen.4539

Keywords:

Co sputtering magnetron, Stainless steel, Nickel-Zinc, Characterization, Thin film

Abstract

By serving as a catalyst and boosting reaction efficiency in procedures like water electrolysis, biomass gasification, and photochemical reactions, nickel-based component plays a crucial part in the production of hydrogen. The purpose of this work was to use Magnetron Sputtering technology to develop nickel-zinc thin films on a stainless-steel substrate. Scanning electron microscopy, XPS spectroscopy, X-ray diffraction, and the electron probe micro-analyzer (EPMA) were used to examine the surface morphology, crystal structure, and chemical composition of the Ni-Zn thin films respectively.According to the found results, we confirm that the Nickel Zinc thin film was well deposited on stainless steel and it can be applied on different application especially on hydrogen production.

References

1. Xia Chen, Zhengyuan Zhang, YingChen Yang, Bochen Hu, Qian Wu, Weiqiang Fan, Jinhui Hao, Weidong Shi (2024) NiCu-based catalysts with high selectivity for electro–oxidation of glucose to formic acid Chemical Engineering Science Volume 291, 5 June 2024, Page 119937

2. Chen, X., Zhang, Z., Yang, Y., Hu, B., Wu, Q., Fan, W., ... & Shi, W. (2024). NiCu-based catalysts with high selectivity for electro–oxidation of glucose to formic acid. Chemical Engineering Science, 291, 119937. DOI: https://doi.org/10.1016/j.ces.2024.119937

3. Medrano-Banda, A., Ginoux, E., Faverge, T., Oshchepkov, A., Bonnefont, A., Chatenet, M., ... & Savinova, E. (2024). Electrochemical oxidation of glucose in alkaline environment—A comparative study of Ni and Au electrodes. Electrochimica Acta, 487, 144159. DOI: https://doi.org/10.1016/j.electacta.2024.144159

4. Bello, I. T., Raza, H., Michael, A. T., Muneeswara, M., Tewari, N., Bingsen, W., ... & Boles, S. T. (2025). Charging Ahead: The Evolution and Reliability of Nickel‐Zinc Battery Solutions. EcoMat, 7(1), e12505. DOI: https://doi.org/10.1002/eom2.12505

5. Feng, S., Liu, J., Zhao, L., Ma, X., Liu, C., Jiang, S., ... & Yang, W. (2025). Low‐Curvature Wood‐Derived Thick Electrodes with High Capacity via In Situ Grown Nanoflower‐Like Ni/Co Bimetallic MOFs for Aqueous Nickel–Zinc Battery. Advanced Functional Materials, e22595. DOI: https://doi.org/10.1002/adfm.202522595

6. Zheng, L., Yi, F., Liang, J., Lu, M., Kong, J., Gao, A., & Shu, D. (2025). Construction of Low-Crystallinity Three-Dimensional Flower-like Cobalt-Doped Nickel Hydroxide for High-Performance Nickel–Zinc Batteries. ACS Applied Materials & Interfaces, 17(5), 7793-7803. DOI: https://doi.org/10.1021/acsami.4c19500

7. Sonntag, B., Dingwerth, B., Vogel, R., & Scheller, B. (2010). Cyanide formation in zinc-nickel electroplating. Galvanotechnik, 101(5), 992-996.

8. Townsend, H. E. (1991, March). Coated Steel Sheets for Corrosion-Resistant Automobiles. In CORROSION 1991 (pp. 1-20). Association for Materials Protection and Performance. DOI: https://doi.org/10.5006/C1991-91416

9. Divisek, J., Malinowski, P., Mergel, J., & Schmitz, H. (1988). Improved components for advanced alkaline water electrolysis. International journal of hydrogen energy, 13(3), 141-150. DOI: https://doi.org/10.1016/0360-3199(88)90014-6

10. De Giz, M. J., Machado, S. A. S., Avaca, L. A., & Gonzalez, E. R. (1992). High area Ni-Zn and Ni-Co-Zn codeposits as hydrogen electrodes in alkaline solutions. Journal of applied electrochemistry, 22(10), 973-977. DOI: https://doi.org/10.1007/BF01024146

11. Sheela, G., Pushpavanam, M., & Pushpavanam, S. (2002). Zinc–nickel alloy electrodeposits for water electrolysis. International journal of hydrogen energy, 27(6), 627-633. DOI: https://doi.org/10.1016/S0360-3199(01)00170-7

12. Müller, C., Sarret, M., & Benballa, M. (2001). Some peculiarities in the codeposition of zinc–nickel alloys. Electrochimica Acta, 46(18), 2811-2817. DOI: https://doi.org/10.1016/S0013-4686(01)00493-5

13. Raj, I. A., & Vasu, K. I. (1992). Transition metal-based cathodes for hydrogen evolution in alkaline solution: electrocatalysis on nickel-based ternary electrolytic codeposits. Journal of applied electrochemistry, 22(5), 471-477. DOI: https://doi.org/10.1007/BF01077551

14. Giridhar, J., & Van Ooij, W. J. (1992). Study of Zn-Ni and Zn-Co alloy coatings electrodeposited on steel strips II: Corrosion, dezincification and sulfidation of the alloy coatings. Surface and Coatings Technology, 53(1), 35-47. DOI: https://doi.org/10.1016/0257-8972(92)90101-F

15. Alfantazi, A. M., Page, J., & Erb, U. (1996). Pulse plating of Zn-Ni alloy coatings. Journal of applied electrochemistry, 26(12), 1225-1234. DOI: https://doi.org/10.1007/BF00249924

16. Sohi, M. H., & Jalali, M. (2003). Study of the corrosion properties of zinc–nickel alloy electrodeposits before and after chromating. Journal of Materials Processing Technology, 138(1-3), 63-66. DOI: https://doi.org/10.1016/S0924-0136(03)00050-5

17. Wharton, J. A., Wilcox, G. D., & Baldwin, K. R. (1996). Non-chromate conversion coating treatments for electrodeposited zinc-nickel alloys. Transactions of the IMF, 74(6), 210-213. DOI: https://doi.org/10.1080/00202967.1996.11871128

18. Zhang, R., Wang, X., Yu, S., Wen, T., Zhu, X., Yang, F., ... & Hu, W. (2017). Ternary NiCo2Px nanowires as pH‐universal electrocatalysts for highly efficient hydrogen evolution reaction. Advanced materials, 29(9), 1605502. DOI: https://doi.org/10.1002/adma.201605502

19. Xie, L., Liu, Q., Shi, X., Asiri, A. M., Luo, Y., & Sun, X. (2018). Superior alkaline hydrogen evolution electrocatalysis enabled by an ultrafine PtNi nanoparticle-decorated Ni nanoarray with ultralow Pt loading. Inorganic Chemistry Frontiers, 5(6), 1365-1369. DOI: https://doi.org/10.1039/C8QI00120K

20. Zhao, Z., Liu, H., Gao, W., Xue, W., Liu, Z., Huang, J., ... & Huang, Y. (2018). Surface-engineered PtNi-O nanostructure with record-high performance for electrocatalytic hydrogen evolution reaction. Journal of the American Chemical Society, 140(29), 9046-9050. DOI: https://doi.org/10.1021/jacs.8b04770

21. Garcés-Pineda, F. A., Blasco-Ahicart, M., Nieto-Castro, D., López, N., & Galán-Mascarós, J. R. (2019). Direct magnetic enhancement of electrocatalytic water oxidation in alkaline media. Nature Energy, 4(6), 519-525. DOI: https://doi.org/10.1038/s41560-019-0404-4

22. Wang, Y., Zhang, L., Yin, K., Zhang, J., Gao, H., Liu, N., ... & Zhang, Z. (2019). Nanoporous iridium-based alloy nanowires as highly efficient electrocatalysts toward acidic oxygen evolution reaction. ACS applied materials & interfaces, 11(43), 39728-39736. DOI: https://doi.org/10.1021/acsami.9b09412

23. Park, J., Sa, Y. J., Baik, H., Kwon, T., Joo, S. H., & Lee, K. (2017). Iridium-based multimetallic nanoframe@ nanoframe structure: an efficient and robust electrocatalyst toward oxygen evolution reaction. ACS nano, 11(6), 5500-5509. DOI: https://doi.org/10.1021/acsnano.7b00233

24. Bar-Hen, A., Hettler, S., Ramasubramaniam, A., Arenal, R., Bar-Ziv, R., & Sadan, M. B. (2022). Catalysts for the hydrogen evolution reaction in alkaline medium: Configuring a cooperative mechanism at the Ag-Ag2S-MoS2 interface. Journal of Energy Chemistry, 74, 481-488. DOI: https://doi.org/10.1016/j.jechem.2022.07.020

25. Bayram, O., Sener, E., İgman, E. et al. Investigation of structural, morphological and optical properties of Nickel-doped Zinc oxide thin films fabricated by co-sputtering. J Mater Sci: Mater Electron 30, 3452–3458 (2019). https://doi.org/10.1007/s10854-018-00620-2 DOI: https://doi.org/10.1007/s10854-018-00620-2

26. Shafiq ullah, Amin Badshah, Fiaz Ahmed, Ramsha Raza, Ataf Ali Altaf, Rizwan Hussain,Electrodeposited Zinc Electrodes for High Current Zn/AgO Bipolar Batteries,International Journal of Electrochemical Science,Volume 6, Issue 9,2011,Pages 3801 3811,https://doi.org/10.1016/S1452-3981(23)18290-3. DOI: https://doi.org/10.1016/S1452-3981(23)18290-3

27. Kobbi Souhila ,BADJI Mouna Sirine, Elaboration, caractérisation, et activation des couches Ni-Zn riches en Ni. Étude de leurs performances dans a production de l'hydrogène vert ,master/2024 ; USTHB.

28. Diafi, M. ., Benramache, S. , Temam, E. G. , Lakhdar, A. M. ., & Gasmi, B. . (2016). Study of zn-ni alloy coatingsmodified by nano-al2o3 particles incorporation. Acta Metallurgica Slovaca, 22(3), 171–180. https://doi.org/10.12776/ams.v22i3.706 DOI: https://doi.org/10.12776/ams.v22i3.706

29. Shouxu Wang, Ruiqi Shen, Cheng Yang, Yinghua Ye, Yan Hu, Chuangxin Li,Fabrication, characterization, and application in nanoenergetic materials of uncracked nano porous silicon thick films,Applied Surface Science,Volume 265,2013,Pages 4-9,https://doi.org/10.1016/j.apsusc.2012.09.148. DOI: https://doi.org/10.1016/j.apsusc.2012.09.148

30. Zinc Nanoparticles at Intercrystallite Sites of (Cu0.5Tl0.5)Ba2Ca3Cu4O12−

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Published

2025-12-27

How to Cite

Samy Anas, Naima Zaourar Boutarek, Philippe David, Eric Mossang, Samir Mansour, & Faouzi Messaoud. (2025). Elaboration and Characterization of Ni-Zn Thin Films on AICI 430 stainless steel by Co-Sputtering Magnetron . International Journal of Computational and Experimental Science and Engineering, 11(4). https://doi.org/10.22399/ijcesen.4539

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